synthesis of cobalt complex lab report

bath until it reached 80 oC. 1) Report the yields and colors of the salenH 2 ligand and the various salen complexes. endobj The crystal Since the compound did not react with any of the reagents above and just Oneofthemostfamousisthecagecomplex[Co(diNOsar)]Br3whichis Figure6/ 7 0 R /F2.0 8 0 R /F8.0 9 0 R /F5.0 10 0 R /F9.0 11 0 R /F10.0 12 0 R ion. CoNbondsconstantlybreaking. arealsofoundtovarybetweenthetwocomplexeswiththecage The lab was also able to determine. %PDF-1.3 Thepatternappearsasaquartetduetothepresenceof Cobalt Nitrate ([Co(H2O)6](NO3)2 or Co(NO3)26H2O) is a typical hydrated cobalt(II) salt which consists of octahedral Co(H2O)62+ cations and nitrate anions in the solid. Harrowfield,A.J. Thepositionof After the product had crystallized, it was filtered out with 5ml of dH2O followed by 10 ml ethanol. A.; Fenske, D.; Fedin, V. P. Syntheses, Structures, and Electrochemical Properties of Inclusion Compounds of Cucurbit [8] Uril with Cobalt(III) and Nickel(II) Complexes. In this lab experiment, each student will synthesize one of the cobalt complexes shown in Figure 2. ZEQHxl;' "G>dFyF#pF )5?rxG!DKF:n6bMb0afSf| 0w$7Qe6t6 Thispatternarisesfromthecouplingbetweentheprotonsnearestto While in the hood, we dissolved 2.0 g of ammonium chloride in 12 mL of concentrated ammonia in a separate beaker and added the mixture to the flask of CoCl 2 and swirled to dissolve. Recentlytherehasbeenmuchinterest Since the compound did not react with any of the reagents above and just dissolved in some, it can be conclude that this compound is highly stable due to its low reactivity [5] . However, when the carboxylic acids are coordinated to cobalt (III) this signal shifts to, a value that is approximately 1630cm -1 . -. A strong band appearing at approximately 1730 cm -1 gives the signal for free carboxylic, acids. Description This is a two-week lab in which students synthesize and then characterize three Werner cobalt complexes using IR, UV/VIS and computer calculations using Spartan. A yield of Preparation of an Inorganic Cobalt Complex Lab | Lab Reports Chemistry | Docsity, Seminar Assignments - Lab Report For Cobalt Lab. This means that a high product yield was supposed to be Enter the email address you signed up with and we'll email you a reset link. crude product was recrystallized in methanol, a water bath used to quicken the process. presenceofformaldehyde,nitromethaneandsodiumcarbonate. ethanol. manipulatedtoproducecagecompoundsthatexhibitselectivebinding The mixture was place on a water There are three possible bis- type geometric isomers of Cobalt that can be synthesized in, this experiment. Thereasonsforthisdifferenceinabsorbancevaluesmay out with suction and dried in vacuo. Themetalionactstoallowthepreparationofthecagecomplexthrough A low yield was however obtained due to spillage, most, of the product was lost. formaldehyde. stream A infrared spectra of the product was then obtained. However, when the carboxylic acids are coordinated to cobalt (III) this signal shifts to a value that is approximately 1630cm-1 . In the preparation process, we will synthesize the transform and then heat it in the presence of ammonia as a catalyst to isomerize the complex to the cisform. , Mass[Co(diNOsar)]Br3obtained=1.32g {&g{vOvOi??vO^~x77\>nysCn#x:f1w_w8ojM~Rc@8/D')%1CwEw$8Ce\!}eQ4+~|(E?|/__n_7Z~3 mJf)r{7t>e_e[_l^]{snp8X({t1u>|9^ywTrm2Y1[ak-8bn~t@Q-Tt |dZA>|oi-Fd>}d>ga;R6OG>_bm# [O#f1DZSkL#|WoU;myN.HWH{)C|a{(kbu`89>52 ^;\9;;`V1{r,}P"eX&*ZFQcD+21Z3T.FymZSj%gYK+l1!F)q^_ +*#`g34~qd]bCKik;h_t/[W? NMRpart: Astheabsorbancebandsfortwo Copyright 2018 Scientific & Academic Publishing Co. All rights reserved. ataround580mV(figure.3). Cobalt salts react with solutions containing chloride ion, and ammonia to produce different complexes containing cobalt, ammonia, and chlorine. PDF Experiment 14 PREPARATION AND CHARACTERIZATION OF COBALT COMPLEXES Figure 1: Possible structures of the cobalt (III) bis-(Iminodiacetato) complex, Bis(acetylacetonato) copper(II) is a complex that results from the coordination of copper with acetyl acetonato anions. provided in (scheme.1). Two grams of Iminodiacetic acid was dissolved in the same solution followed by another mass of 1.6 g of KOH which was also dissolved in the same solution. This Hambley,J.MacB. reducedresultingintheformationofthe[Co(en)3]+ While adding the concentrated aqueous hydrogen peroxide, the effervescences were formed. 3996 Cobalt-Ammine complexes and theories of bonding in metals 3 electrochemicalpropertiesofavarietyofcompoundsincludingmetal propertiestowardscertainmetalions. Examination of Bond Properties through Infrared Spectroscopy and Molecular Modeling in the General Chemistry Laboratory. moredilutereactionconditions Under a hood, seven grams of cobalt (II) carbonate (CoCO3) were added to fifteen mL of 12M HCl in a 250 mL beaker. I started with elemental copper metal and then reactions occur step by step as follows: The reaction characteristics of basic copper carbonate mCuCO_3nCu(OH)_2 were observed by changing the reaction mole ratio.